Cream together butter, sugar, sourdough starter.
With the stand mixer on low, cream in one egg yolk at a time until just combined.
Mix in the egg whites.
Incorporate the buttermilk and vanilla.
Using a sifter, sift in the cake flour, baking powder, baking soda, and salt.
Mix until well incorporated and no dry parts remain. There may be a few clumps from the buttermilk, this is fine.
For longer fermentation, cover the bowl with an airtight lid and place in the refrigerator for at least 8 hours or overnight.
When ready to bake, preheat the oven to 350 degrees F.
Line a cupcake tin with cupcake liners or generously butter the tin.
Fill the cupcake liners 3/4 of the way (about 1/4 cup for standard cupcakes).
Place the cupcakes in the preheated oven and bake for 28-30 minutes (until a toothpick or baking tester comes out clean when inserted into the middle of a cupcake).
Once the cupcakes are baked through and golden on top, remove from the oven to a wire cooling rack.
Allow the cupcakes to cool on the rack for 15 minutes.
Remove cupcakes from the tin to fully cool on the cooling rack.
After the cupcakes have cooled, frost the tops and add garnishes of your choice.
Happy baking!